?? ????????, ?????? ?? ???????? ???????? ????? ????, ?? ??? ?????????? ????? ???? ?? ??????? ??? ?? ????????????? ????? ????? ????? ?????? ?????. ?? ??? ????? ????????, ?????????? ???? ???????? ??????????, ????? ??????? ?????????????, ????? ??? ?????????? ??? ????? ???? ???????, ??????, ?? ??? ?????????? ??????????? ?????? ?? ???????? ??? ????? ?????. ??????? ?? ???? ??? ?? (??? ?? ??????????, ??????, ??? ?.) ??? ???? ?? (??? ?? ???????? ??, ??????? ??) ????? ??????? ????, ??????? ?? ?? ???? ?? ????????? ?? ?????????? ??? ???, ??????? ?? ???????? ????? 6 ???????????? ??????? ??? ????:

?) ???? ?? ?????? (????????): ???????, ????? ???????, ???????? ?????????, ???????? ?????????, ?-?????????-?-??????? ?????????, ??? (?-??????-?-???????) ??????????, ?????? ????????????????? (??????), ?.;

?) ????? ???: ?????? ????????? (MSG), ?????? ?????? (IMP), ?????? ????????? (GMP), ?????? ?????? + ?????? ????????? (I+ G), ?????????? ???????? (MSS), ????????? ???????? (DSS), ?.;

?) ???????? ?????? ???? ??? ??????? ??????? ?????: ??? ?? ?????? ???, ??? ?? ??? ???? ?????????? ?????? ????, ????? ????? ??????? ?????;

?) ??????? ?????????? ??????? ?????? ???: ??? ?? ??????????? ????? ??????? ??? ??????? ?? ????????? ??????????? ???? ??? ???????? ?????????? ??????? ?????;

?) ??? ???????? ?? ??? ?????: ??? ?? ??????????? ???? ?????? ???????? ??????? ???? ??? ?????? ????? ????? ??? ????????? ???? ?????? ???????? ???? ??? ???????? ????? ?????.

??????? ?? ?????????? ???????? ????? ??????? ????:

?) ?????? ??? ???, ????? ???????? ?????? ??????? ???;

?) ????? ???????? ????? ????? ??? ??? ???? ????? ??? ?????? ?????????? ???? ??? ???? ???? ??? ????, ????? ?? ????? ??????? ?????? ???? ????, ??????? ????? ??????????????? ?????? ??????? ????? ??? ????, ??????????????? ??????? ??????????? ?????? ???? ??? ?????? ???? ??? ????? ???????? ??????? ????? ??? ????;

?) ??? ?????? ?????????? ?????? ??? ??? ????? ????? ????????????? ?????? ????? ????? ?????? ??? ???, ???????? ???? ??? ????;

?) ???? ????????? ?????? ???? ?? ?????????? ?????? ??? ????? ?? ??????? ???????? ?????? ?????? ????? ????, ???????? ????? ???????, ??, ?????? ??? ????? ?????? ????????? ??? ????? ????;

?) ???? ?? ?????????? ????????????? ????? ?????? ???? ???? ??? ?? ????????? ?????????? ??? ?????????? ??????????? ???? ?????????, ?????? ??????? ??? ?????? ?????? ???? ??? ?????;

?) ????????? ?????? ?????? ???????? ?????? ????. ???? ????????? ???? ?????? ???????? ????????? ??????? ???? ???????? ?????? ????? ?????, ??? ?? ???????, ????? ???????, ?., ?? ???? ????? ????? ???????? ????????? ?????? ??? ?????, ??? ?? ???????? ?????????, ??????, ?.;

?) ????? ???????????????? ??????????? ?????? ????????, ?? ???? ????? ?????? ?????.

????? ???? ?? ?????????? ?????????? ?????

?, ??????????? ?? ?????? ????

(?) ??????? ??? ????? ??????? ?? ?????? ????? ?????????? ????????? ???? ????, ???? ???? ???????????? GC/MS ?????????? ??? ????? ??? ?? ???? ??????????? ????? ????? ????? ????????? ?????? ??? ????? ????, ?% ?? ??% ?????? ??????? ?????? (???? ?????? ???????????? ?????????? ?????? ???????? ???? ???, ???????????? ?????). ??????? (???????, ?????????), ??????????? ???????? ???, ???????, ???????, ???????? ??? ?-?????????????????? ?????, ???? ????? ???? ????? ?? ????? ????? ???, ?????? ?????? ????? ????? ?????? ????, ??????, ?? ℃ ?? ?????????? ???? ????. ???????? ???????? ?????-?????? ?????, ???? ????, ??????????? ??????. ????? ??????? (????????????), ???????????????? ?-???? ???????????? ????? ?????? ????? ??????, ???????? ??????? ?????? ??? ?????? ????? ???, ???? ???????? ??? ??? ?? ??? ??? ?????? ????? ???. ?????? ??????? ????????? ????, ?????? ??? ????????? ???????? (PG) ???????? ????? ? ???????????? ???? ???? ??????: ?) ??????????? ????? ???????????? ???? ??? ?????? ???????? ?????? ??? ?????? ????, ?????? ?????? ?????? ?????? ????; ?) ????????? ??????????, ????? ???????? ?????? ?????? ????, ????? ??????? ??????????, ????? ???????????? ??????? ?????????? ?????? ??? ????; ?) ????? ????????? ????? ???????? ?????? ????????????? ?????? ?-? ?? ???? ??? ????????? ???? ?????? ??? ??? ???? ??? ????; ?) I + G, MSG, MCP ??? ??? ????????? ???????? ?????????, ?? ?????? ????? ????.

(b) MCPMCP, ?????? 3-??????-1, 2-?????????????????? ????? 3-??????-2-???????????-2-?????????????-1-?? ???????? ????? ????, ?? ???? ??? ???? ???????? ?????? ????? ???? ????? ?????? ????? ???, ?????? ?????? ????? ????? ???????. ???? ????????? ????????? ?????? ???????? ????? ???. MCP ????? ??????? ??? ????? ??????? ?????? ????? ??????? ????, ????? ??? ????? ?????. ???? ??????????? ??? ??????????, MCP ????? ???? ????? ??? ??? ?????? ?????????? ??????????? ???? ??? ?? ???????? ???? ?? ??????? ????.

(?) ???????? ?????????, ?????? ???? ?????????, ?-??????? ?????????????? ????? ???????. ???? ?????????????, ?????? ??? ?????? ??????? ??? ???? ??? ?????? ?? ???? ???? ???? ?????? ?? ???? ??? ?????????? ??? ????. ???? ?????? ?????????? ???????? ???????? ?% ???????? ????????? ?????????????? ????, ????????? ??????? (????????????) ????? ?? ???? ??? ??????? ?????? ?? ????. ???? ????????? ???????? GC/MS ?????????? ???????? ??????????? ???????? ??? ???????? ????? ??? ???? ???????? ???????? ??????????? ?????? ????? ?????? ???? ??? ????? ??? ???????? ????? ????????? ????? ????. ????????? ??????, ???????? ????????? ?% ???????? ????? ???? ???? ???? ??? ???? ?????? ???????? ????????? ???? ????? ????.

(?) ?????????; ?????????) ???????? ??? ?, ?-?????????-?-???????????-? (???) -?????????, ?? ??????? ?? ????????, ?? ????????, ???????? ?????? ???. ???? ???? ???????? ??????????, ?? ?????? ???? ??? ?????? ???????? ???? ????, ?????? ?????? ????????? ????? ???????. ?????????????? ???????? ????, ??????????????? ????? ????, ?????? ???????? ??? ????? ?????? ????? ????? ???? ????, ?????? ?????, ???????? ?????? ????, ????? ???? ??? ??? ????? ???? ???? ??? ?????? ?? ???????? ???????? ??? ????????? ????? ????. ??????????? ?? ??? ????? ???????????? ??? ?????? ??????? ??????? ?????????? ????? ??????????? ?.? ?? ? ??? ??? ??????????? ?? ?? ?? ????????? ??????? ???. ???? ????????? ???????? ????/???? ??????????, ??????????? ???????? ????? ??? ??? ?????? ?????? ?? ??????????? ?% ???? ????? ??? ????. ????????, ????????? ?? ????????? ????? ?? ?? ????????? ????? ????? ???, ?? ???????, ???????, ??????? ??????? ??? ??? ?????????? ??????????? ???? ????????? ????? ?????? ???? ??? ???? ??? ??? ??? ???????? ????????? ??????? ???? ??? ????. ???? ?????? ??????? ????????????, ???? ??????????? ????????? ????????? ????? ?????????? ??? ?????? ???? ???? ??? ???????????? ?? ???? ????. ??? ??????????? ????????? ????????? ?? ??? ?? ????????????? ???? ???? ??? ????? ?????????? ??? ?? ????????????? ?????, ???????? ??????? ?? ???? ????, ???? ??? ???? ????. ?????????, (I + G) ??? MSG ???? ??????? ??????? ????? 1 ????? ???????? ????.

(?) ????? ???????? ??? ???????????? ?????? ?????? ??? ?????? ???????? ????: ?-??????-?-????? ?????????, ??? (?-??????-?-?????) ??????????, ?-??????-?-??????-?????????, ?-??????-?-?????????????????? ?????????, ?. ?? ????????? ??????????? ???? ??? ????????? ??????? ?? ????, ????? ??????? ????? ????? ????????, ?? ???? ??? ??? ???????? ?????? ??? ?????.

???, ????? ???? ????

(?) MSGMSG ?????? MSG, ?????? L-????????? ??????, ?????? ????????? ????? ???????. MSG ????? ?????? ???, ?????, ??? ??? ???? ??????, ??? ????? ??????? 0.014% ???. MSG ???????? ??????? ?????? ??? ?????? ????????? ????? ???? ??? ????? ??? ????????????? ??? ?????? ??????. ????? ??????? ???? ???, ??? ??????? ?????? ????? ??????? ??????????? ???? ??? ????? ???? ???? ??? ???? ????.

MSG ?? IMP, GMP ??? (I + G) ?? ???????????? ?????? ????. (MSG + IMP) 0.05 g/L ???????? ??????????, ?????? MSG∶IMP = 1∶1 ????, ?????? ????? ???? ????????????? ???????; MSG ??? IMP ???? ????????, IMP ?? ???????? ??? ??????????? 50% ?????? ????? ??? ??????? ??????? ????? ????????? ?????? ?????. IMP ?? ???????? ??? 50% ???? 100% ?????? ????? ??? ????? ????????? ?????? ??????? ??????? ??? ????.

MSG ???????? (I + G) ????? ?????? ????? MSG ???? ???? ????, 99% MSG+ 1% (I + G) 2 ?? ?????? ????, 98% MSG+ 2% (I + G) 3.5 ?? ?????? ????; 96% MSG+ 4% (I + G) 5 ?? ?????? ????. ????????? ??????? ??????, MSG ???????? (I + G) ???? ?????? ???? ??? ??????? ????????? ????? 1 ????? ???????? ???.

(?) IMP, GMP ??? (I + G) IMP ??? GMP ?? ??????, ??????? ???? ??? ???? ????????? ????? ??? ??????????? ?????????????? ??? ???????, ??, ?????? ????? ?????? ???? ??? ??????? ???? ????????? ?????????? ?????? ???????? ??????. IMP ??? GMP ????? ??????? ????? ?? ???? ??? GMP ?? ??????? ??????? IMP ?????? ?????? 3 ?? ????? ???? ??? ?? ??????? ?????? ???? ???????????????? ?????? ???? (??????, I + G, IMP ??? GMP ????????? 50% ????). MSG, IMP, GMP, (I + G) ??????? ?? ???? ?????, ???????? ???? ????, ??????? ?? ????? ???? ??? ?????? ????, ???????? ??? ????? ???? ??????? ??? ????.

(?) MSS ??? DSSMSS, DSS ??????????? ????? ??? ????? ??? ??????? ?? ????, ?????? ?? ???????????????? ????????? ?????? ????? ????? ????, ??? ??????? (??? ?? ????? ????, ??????, ???????, ?????????, ??????, ??????? ?.) ??????? ????? ???, ??????? ??????????????? ?? ???????? ?????? ?????? ??? ?????. ???????? MSG ???? ??????????? ?????? ???.

?. ???????? ?????? ??? ????? ?????? ??????? ???

?????? ????? ?????? ?????? ?????? ??? ?????? ?????? ???. ? ????????? ????? ?????? ??? ??? ??? ?????, ???? ?? ?????? ????? ???????? ??????????? (??? ?? ????????????????, ??????, ???????????????, ???????, ?-????????????, ?.), ???? ????? (?????, ?????????, ?.) ??? ?? ?????? ????? ???????? ??? ?????? ?????? ?????. ?????, ??? ???????????, ?????? ?????? ??? ??? ?????? ??? ?????. ??????? ???????????????, ????????, ???????????, ???????, ????, ????????, ?????, ?????????, ??????????, ????????, ??????????, ??????????, ???????????, ?????????, ?????????, ????????? ??? ????????? ??? ??? ?? ????????? ??? ?????? ?????????? ?????? ???. ?????-?? ????????? ????????? ???????? ????? ????? ????? ??? ?????? ????? ???????? ?????? ????. ?? ???????? ?????????? ???????? ?????? ??? ??????? ????, ?? ????? ?????? ??? ????????? ???? ?????? ???, ?????? ?? ??????????? ???? ?????????? ???? ????, ???????? ????? ?????? ??? ???????? ???????? ????. ???? ???????????????? ?????? ???????? ??????? ????? ????? ???? ?????, ?????? ??? ?????? ?? ???????????? ????? ????, ???????? ?????????? ???????? ????? ???????. ???????? ??? ???????? ???????????????, ??? ?????? ?? ????? ?????? ??? ????. ?????? ???????? ??? ?????? ????? ?????? ????? ???? ????? ???????? ?????? ????, ?????? ?? ?????? ???????? ?????? ????.

????, ?? ???????? ?????? ???? ?????????? ????????? ???????????

?? ???????? ??????????? ???? ????????????? ??????? ???? ???, ??????????: ?) VB1 → bis (2-??????-3-?????????) ??????????; ?) α-???????????? ????? + (NH4) 2S →H2S, ?.; ?) ????????? + (NH4) 2S →H2S, ?.; ?) ??????????? ??? ??????? ?????????? ????????? + (NH4) 2S →H2S, ?.

????????? ????? ????? ??? ?????????? ??? ?????? ????, ?????????? ??? ?????? ?????????????, ??????? ?? ???????? ?????? ????? ?????? ???. ?????, ???????? ?? ???????? ?????? ????????? ??????? ???? ???? ??? ??? ????, ?????????????, MSG, (I + G), ?????????, ??????? ??? ????? ??????? ????? ?????????? ????????? ?????? ????? ????, MSS, DSS ????????? ??????, ?????? ??? ??????? ????, ??????, ???, ????? ??? ??? ?????????? ??????? ????? ???.